If Pokémon Talked: Generation II
KittyLuv090 for Quilava/Typhlosion (Female)
Quilava is the evolved form of Cyndaquil. It has more of a burning passion for battle than it's previous evolution. It will also intimidate its foes with its flames. I would imagine Quilava having a young energetic teenage voice. I may have listed young adult for this, but I would recommend more of a teenage voice coming from this Pokémon.
Typhlosion is Cyndaquil's final evolution. Once its rage intensifies, anything that touches this Pokémon gets burned to a crisp. It also hides a secret move that can cause gigantic explosions. With this Pokémon's voice, it would have more of an adult voice and I would consider it having the type of voice that makes it sound ill-tempered and always prepared for a battle. This role will also contain quite a lot of yelling.
Quilava: I never get burned! I have flames of my own! Wanna see me let some flames out? Or are you too scared to see 'em?
Typhlosion: Anything that touches me gets burned to cinders! So I would suggest you back off when my rage unleashes.
I have decided to cast you for Quilava, and cast your sister as Typhlosion! :)